2,6-Dibromonaphthalene → HCID 68554435, compound

HRID 2271373Notes

Reaction equation

HRID 2271373 reaction equation
[C:1]1([C:7]2[C:21]3[C:20]4[C:22]5[C:16]([CH:17]=[CH:18][CH:19]=4)=[C:15](B(O)O)[CH:14]=[CH:13][C:12]=5[C:11]=3[C:10]([C:26]3[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=3)=[C:9]3[CH:32]=[CH:33][CH:34]=[CH:35][C:8]=23)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Br[C:37]1[CH:46]=[CH:45][C:44]2[C:39](=[CH:40][CH:41]=[C:42]([Br:47])[CH:43]=2)[CH:38]=1>>[Br:47][C:42]1[CH:43]=[C:44]2[C:39](=[CH:40][CH:41]=1)[CH:38]=[C:37]([C:15]1[CH:14]=[CH:13][C:12]3=[C:22]4[C:16]=1[CH:17]=[CH:18][CH:19]=[C:20]4[C:21]1[C:7]([C:1]4[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=4)=[C:8]4[CH:35]=[CH:34][CH:33]=[CH:32][C:9]4=[C:10]([C:26]4[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=4)[C:11]=13)[CH:46]=[CH:45]2

Participants

3

Reactant 2

HCID 6405912,6-DibromonaphthaleneHCID 21043382HCID 21043382, compound

Product 1

HCID 68554435HCID 68554435, compound

Procedure

It was carried out in a similar manner as Synthesis Example 1 except that 7,12-diphenylbenzo[k]fluoranthene-3-yl boronic acid was employed instead of 9,9-dimethyl-911-fluorene-2-yl boronic acid, and that 2,6-dibromo-naphthalene was employed instead of 3-bromo-7,12-dibenzo[k]fluoranthene in Synthesis Example 1 to obtain 3-(6-bromonaphthalen-2-yl)-7,12-diphenylbenzo[k]fluoranthene.

Sources & evidence

ORD record
ord-9ad7a3c22fca468382d17d2abab2041b
Source dataset
uspto-grants-2015_09
Patent number
US09120748B2

Reaction notes

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