4-Cyanophenylboronic acid → HCID 58988841, compound
Reaction equation
[C:1]([C:3]1[CH:8]=[CH:7][C:6](B(O)O)=[CH:5][CH:4]=1)#[N:2].Br[C:13]1[CH:14]=[C:15]2[C:20](=[CH:21][CH:22]=1)[CH:19]=[C:18]([C:23]1[CH:37]=[CH:36][C:35]3=[C:38]4[C:24]=1[CH:25]=[CH:26][CH:27]=[C:28]4[C:29]1[C:30]([C:49]4[CH:54]=[CH:53][CH:52]=[CH:51][CH:50]=4)=[C:31]4[CH:48]=[CH:47][CH:46]=[CH:45][C:32]4=[C:33]([C:39]4[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=4)[C:34]=13)[CH:17]=[CH:16]2>>[C:1]([C:3]1[CH:8]=[CH:7][C:6]([C:13]2[CH:14]=[C:15]3[C:20](=[CH:21][CH:22]=2)[CH:19]=[C:18]([C:23]2[CH:37]=[CH:36][C:35]4=[C:38]5[C:24]=2[CH:25]=[CH:26][CH:27]=[C:28]5[C:29]2[C:30]([C:49]5[CH:54]=[CH:53][CH:52]=[CH:51][CH:50]=5)=[C:31]5[CH:48]=[CH:47][CH:46]=[CH:45][C:32]5=[C:33]([C:39]5[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=5)[C:34]=24)[CH:17]=[CH:16]3)=[CH:5][CH:4]=1)#[N:2]Participants
3
Procedure
It was carried out in a similar manner as Synthesis Example 1 except that 4-cyanophenyl boronic acid was employed instead of 9,9-dimethyl-9H-fluorene-2-yl boronic acid, and that 3-(6-bromonaphthalen-2-yl)-7,12-diphenylbenzo[k]fluoranthene was employed instead of 3-bromo-7,12-dibenzo[k]fluoranthene in Synthesis Example 1 to obtain 3-(6-(4-cyanophenyl)naphthalen-2-yl)-7,12-diphenylbenzo[k]fluoranthene (Compound 5-12).
Sources & evidence
- ORD record
- ord-360c77676cd24a36a757370bc8274e84
- Source dataset
- uspto-grants-2015_09
- Patent number
- US09120748B2
Reaction notes
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