Ethanol → HCID 178524967, compound

HRID 2272639Notes

Reaction equation

HRID 2272639 reaction equation
[OH-].[K+:2].O.[NH:4]1[C:8]([C:9]([O:11]CC)=[O:10])=[N:7][N:6]=[N:5]1.CCO>>[NH:4]1[C:8]([C:9]([O-:11])=[O:10])=[N:7][N:6]=[N:5]1.[K+:2].[K+:2].[NH:4]1[C:8]([C:9]([O-:11])=[O:10])=[N:7][N:6]=[N:5]1

Participants

5

Reactant 4

HCID 702EthanolHCID 962WaterHCID 14797Potassium HydroxideHCID 178470518HCID 178470518, compound

Product 1

HCID 178524967HCID 178524967, compoundYield 128%

Procedure

A solution of potassium hydroxide (1.3 g, 23.2 mmol) in water (4.2 mL, 230 mmol) was added to a solution of ethyl tetrazole-5-carboxylate (1.1 g, 7.7 mmol) in EtOH (24 mL, 410 mmol). A solid product formed immediately and was collected and washed with cold EtOH to yield the title compound (1.5 g).

Workup

  1. customA solid product formed immediately
  2. customwas collected
  3. washwashed with cold EtOH

Sources & evidence

ORD record
ord-4123320637ff41bdb278967af25c313b
Source dataset
uspto-grants-2015_09
Patent number
US09120758B2

Reaction notes

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