Ethanol → HCID 178524967, compound

HRID 2272642Notes

Reaction equation

HRID 2272642 reaction equation
[OH-].[K+:2].O.[NH:4]1[C:8]([C:9]([O:11]CC)=[O:10])=[N:7][N:6]=[N:5]1.CCO>>[NH:4]1[C:8]([C:9]([O-:11])=[O:10])=[N:7][N:6]=[N:5]1.[K+:2].[K+:2].[NH:4]1[C:8]([C:9]([O-:11])=[O:10])=[N:7][N:6]=[N:5]1

Participants

5

Reactant 4

HCID 702EthanolHCID 962WaterHCID 14797Potassium HydroxideHCID 178470518HCID 178470518, compound

Product 1

HCID 178524967HCID 178524967, compoundYield 128%

Procedure

Dipotassium 1H-tetrazole-5-carboxylate was prepared as follows: A solution of potassium hydroxide (1.3 g, 23.2 mmol) in water (4.2 mL, 230 mmol) was added to a solution of ethyl tetrazole-5-carboxylate (1.1 g, 7.7 mmol) in EtOH (24 mL, 410 mmol). The solid product that formed immediately was collected and washed with cold EtOH to yield dipotassium 1H-tetrazole-5-carboxylate (1.5 g).

Workup

  1. customDipotassium 1H-tetrazole-5-carboxylate was prepared
  2. customThe solid product that formed immediately
  3. customwas collected
  4. washwashed with cold EtOH

Sources & evidence

ORD record
ord-8a2910b2df4e4b1fb466176a7bfc1774
Source dataset
uspto-grants-2015_09
Patent number
US09120758B2

Reaction notes

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