Trichlorosilane → HCID 123708636, compound

Participants

Reaction Steps

In an argon atmosphere, a dilithium(N,N′-bis(1,1,3,3-tetramethylbutyl)-1,2-vinylenediaminide) solution prepared according to the procedure and reagent quantities described in Reference Example-11 was added to a hexane (150 mL) solution containing 25.00 g (184.6 mmol) of trichlorosilane, and the mixture was stirred at room temperature for 3 hours. Insoluble matters produced were separated by filtration, and the solvent was removed by distillation from the filtrate under atmospheric pressure. The obtained residue was distilled under reduced pressure (distillation temperature: 125° C./85 Pa) to obtain 2-chloro-1,3-bis(1,1,3,3-tetramethylbutyl)-1,3-diaza-2-silacyclopent-4-ene (Si(tOctNCHCHNtOct)(H)Cl) as a pale yellow liquid (yielded amount: 57.22 g, yield: 90%).

Provenance & Evidence