Ethylamine → HCID 123728622, compound

Participants

Reaction Steps

In an argon atmosphere, 3.40 g (75.5 mmol) of ethylamine was dissolved in 30 mL of hexane, and a solution obtained by dissolving 5.78 g (24.8 mmol) of Si(tBuNCHCHNtBu)(H)Cl in 5 mL of hexane was added thereto at −20° C. After stirring at room temperature for 2 hours, insoluble matters produced were separated by filtration, and the solvent was removed by distillation from the filtrate under atmospheric pressure. The obtained residue was distilled under reduced pressure (distillation temperature: 86° C./4.1×102 Pa) to obtain 1,3-di-tert-butyl-2-ethylamino-1,3-diaza-2-silacyclopent-4-ene (Si(tBuNCHCHNtBu)(H)NHEt) as a pale yellow liquid (yielded amount: 5.77 g, yield: 96%).

Provenance & Evidence