Cyclohexylamine → HCID 124032155, compound

HRID 2273156Notes

Reaction equation

HRID 2273156 reaction equation
Cl[SiH:2]1[N:6]([C:7]([CH3:10])([CH3:9])[CH3:8])[CH:5]=[CH:4][N:3]1[C:11]([CH3:14])([CH3:13])[CH3:12].[CH:15]1([NH2:21])[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16]1>CCCCCC>[CH:15]1([NH:21][SiH:2]2[N:6]([C:7]([CH3:10])([CH3:9])[CH3:8])[CH:5]=[CH:4][N:3]2[C:11]([CH3:14])([CH3:13])[CH3:12])[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16]1

Participants

4

Reactant 2

HCID 7965CyclohexylamineHCID 713346111,3-Di-tert-butyl-2-chloro-2,3-dihydro-1H-1,3,2-diazasilole

Product 1

HCID 124032155HCID 124032155, compoundYield 96%

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

In an argon atmosphere, 5.70 g (24.5 mmol) of Si(tBuNCHCHNtBu)(H)Cl was dissolved in 100 mL of hexane and after adding 4.86 g (49.0 mmol) of cyclohexylamine, the mixture was stirred at room temperature for 4 hours. Insoluble matters produced were separated by filtration, and the solvent was removed by distillation from the filtrate under atmospheric pressure. The obtained residue was sublimated (heating temperature: 160° C./7.0×102 Pa) to obtain 2-cyclohexylamino-1,3-di-tert-butyl-1,3-diaza-2-silacyclopent-4-ene (Si(tBuNCHCHNtBu)(H)NHCy) as a white solid (yielded amount: 6.95 g, yield: 96%).

Workup

  1. customInsoluble matters produced
  2. customwere separated by filtration
  3. customthe solvent was removed by distillation from the filtrate under atmospheric pressure
  4. temperature(heating temperature: 160° C./7.0×102 Pa)
  5. customto obtain

Sources & evidence

ORD record
ord-6b80649311984866b829b19c5dc873c7
Source dataset
uspto-grants-2015_09
Patent number
US09120825B2

Reaction notes

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