Ethylamine → HCID 123737078, compound

Participants

Reaction Steps

In an argon atmosphere, 6.80 g (151 mmol) of ethylamine was dissolved in 20 mL of hexane, and a solution obtained by dissolving 5.26 g (15.2 mmol) of Si(tOctNCHCHNtOct)(H)Cl in 10 mL of hexane was added thereto at −20° C. After stirring at room temperature for 12 hours, insoluble matters produced were separated by filtration, and the solvent was removed by distillation from the filtrate under atmospheric pressure. The obtained residue was distilled under reduced pressure (distillation temperature: 128° C./1.4×102 Pa) to obtain 1,3-bis(1,1,3,3-tetramethylbutyl)-2-ethylamino-1,3-diaza-2-silacyclopent-4-ene (Si(tOctNCHCHNtOct)(H)NHEt) as a pale yellow liquid (yielded amount: 5.22 g, yield: 97%).

Provenance & Evidence