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HRID2277247

反应详情

EQUATION

反应方程式

HRID 2277247 的结构方程式

REACTANTS

反应物

1
结构：O=[N+]([O-])c1ccc(S(=O)(=O)OCC2CC2(F)F)cc1
HCID86731319

未命名化合物

PRODUCTS

生成物

1
结构：O=[N+]([O-])c1ccc(S(=O)(=O)OC[C@H]2CC2(F)F)cc1
HCID86731320

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCCCCC.CCO
溶剂HCID21879635

未命名化合物

PROCEDURE

实验过程

A racemate (48.4 g) of (2,2-difluorocyclopropyl)methyl 4-nitrobenzenesulfonate was resolved by HPLC (column: CHIRALPAK AD (trade name), 50 mmID×500 mL, DAICEL CHEMICAL INDUSTRIES, LTD., mobile phase:hexane/ethanol=50:50) to give the title compound having a shorter retention time (18.4 g). The steric configuration was determined by X ray structure analysis.