Carbazole → 3-Carbazol-9-yl-8,8-dimethyl-8H-indolo[3,2,1-de]acridine

HRID 2277354Notes

Reaction equation

HRID 2277354 reaction equation
Br[C:2]1[CH:7]=[CH:6][C:5]2[N:8]3[C:21]4[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=4[C:15]([CH3:23])([CH3:22])[C:14]4[C:9]3=[C:10]([CH:11]=[CH:12][CH:13]=4)[C:4]=2[CH:3]=1.[CH:24]1[C:36]2[NH:35][C:34]3[C:29](=[CH:30][CH:31]=[CH:32][CH:33]=3)[C:28]=2[CH:27]=[CH:26][CH:25]=1>>[CH:33]1[C:34]2[N:35]([C:2]3[CH:7]=[CH:6][C:5]4[N:8]5[C:21]6[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=6[C:15]([CH3:23])([CH3:22])[C:14]6[C:9]5=[C:10]([CH:11]=[CH:12][CH:13]=6)[C:4]=4[CH:3]=3)[C:36]3[C:28](=[CH:27][CH:26]=[CH:25][CH:24]=3)[C:29]=2[CH:30]=[CH:31][CH:32]=1

Participants

3

Reactant 2

HCID 6854CarbazoleHCID 671095853-Bromo-8,8-dimethyl-8H-indolo[3,2,1-de]acridine

Product 1

HCID 673258093-Carbazol-9-yl-8,8-dimethyl-8H-indolo[3,2,1-de]acridine

Procedure

The compound is synthesised by the same procedure as Example 18 by reaction of 31 g (86.0 mmol) of 3-bromo-8,8-dimethyl-8H-indolo[3,2,1-de]-acridine with 16 g (95.9 mmol) of carbazole.

Sources & evidence

ORD record
ord-057aa4dc49224b889fc0f57623c5bf69
Source dataset
uspto-grants-2015_09
Patent number
US09133119B2

Reaction notes

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