HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylamine → HCID 72546103, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylamine | HCID 674 | — |
| Reactant | Lithium Hexamethyldisilazide | HCID 2733832 | — |
| Reactant | 2-Dicyclohexylphosphino-2',6'-diisopropoxybiphenyl | HCID 16217985 | — |
| Reactant | Ethyl acetate hexane | HCID 21226206 | — |
| Reactant | HCID 86702742 | HCID 86702742 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 72546103 | HCID 72546103 | 62% |
Reaction Steps
Follows general procedure (pag. 13): [RuPhos Palladacyle] (0.0015 g, 0.0021 mmol), LHMDS (0.17 mL of a 1.0 M solution in THF, 0.17 mmol), 5a (0.030 g, 0.087 mmol) in THF (0.3 mL), dimethylamine (0.065 mL of a 2.0 M solution in THF, 0.13 mmol). The title compound was isolated (n-hexane/AcOEt 8:2, 0.019 g, 62% yield) as a yellow solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09133234B2 |
| Source dataset | uspto-grants-2015_09 |
| ORD ID | ord-b5ecbf97d56e41b5a5aa84b2539a74e0 |
| Source note | uspto-grants-2015_09 |