HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylamine → HCID 72546105, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylamine | HCID 674 | — |
| Reactant | Lithium Hexamethyldisilazide | HCID 2733832 | — |
| Reactant | 2-Dicyclohexylphosphino-2',6'-diisopropoxybiphenyl | HCID 16217985 | — |
| Reactant | Diethylether hexane | HCID 21584099 | — |
| Reactant | HCID 86702746 | HCID 86702746 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 72546105 | HCID 72546105 | 71% |
Reaction Steps
Follows general procedure (pag. 13): [RuPhos Palladacyle] (0.0013 g, 0.0018 mmol), LHMDS (0.15 mL of a 1.0 M solution in THF, 0.15 mmol), 5c (0.040 g, 0.075 mmol) in THF (0.3 mL), dimethylamine (0.056 mL of a 2.0 M solution in THF, 0.11 mmol). The title compound was isolated (n-hexane/Et2O 8:2, 0.029 g, 71% yield) as a yellow oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09133234B2 |
| Source dataset | uspto-grants-2015_09 |
| ORD ID | ord-4cbf0dfc320b4fafa428ff84c08441fa |
| Source note | uspto-grants-2015_09 |