HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,1,1,3-Tetrachloropropane → 1,1,3-Trichloropropene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,1,1,3-Tetrachloropropane | HCID 14056 | — |
| Reactant | Chlorine | HCID 24526 | — |
| Product | 1,1,3-Trichloropropene | HCID 17378 | — |
| Product | 1,1,2,3-Tetrachloro-1-propene | HCID 25281 | — |
| Product | 1,1,1,2,3-Pentachloropropane | HCID 13454491 | — |
Reaction Steps
Chlorine conversion was 99%; 1,1,1,3-tetrachloropropane conversion was 99%. The yields of 1,1,3-trichloropropene, 1,1,1,2,3-pentachloropropane, and 1,1,2,3-tetrachloropropene on 1,1,1,3-tetrachloropropane fed were 2.0, 85, and 5.8 percent, respectively. The total yield of four prominent high-boiling byproducts was 3.3 wt % in the reactor effluent. These byproducts are believed to be hexachloropropane, two pentachlorohexene isomers, and hexachlorohexadiene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09139495B2 |
| Source dataset | uspto-grants-2015_09 |
| ORD ID | ord-4aa53ed0a64542e98be405f606742ab4 |
| Source note | uspto-grants-2015_09 |