Sodium Azide → 9-Azidononanoic acid

HRID 2280977Notes

Reaction equation

Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]([OH:12])=[O:11].[N-:13]=[N+:14]=[N-:15].[Na+]>>[N:13]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]([OH:12])=[O:11])=[N+:14]=[N-:15]

Participants

Reactant 2

HCID 33557Sodium Azide

HCID 5482219-Bromononanoic Acid

Product 1

HCID 152305499-Azidononanoic acid

Procedure

Reaction of 9-bromononanoic acid and NaN3, as described for the synthesis of 6, gave 5-azidobutanoic acid 12. Saponification was not necessary. Used without further purification.

Workup

customas described for the synthesis of 6

Sources & evidence

ORD record: ord-d9b92e2526714611a73e20625d7cfa3d
Source dataset: uspto-grants-2015_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09139565B2

Reaction notes

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