HuagongsheHuagongshe Chemistry Print Report · For research reference only
N,N,N',N'-Tetramethylethylenediamine → HCID 86704324, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N,N,N',N'-Tetramethylethylenediamine | HCID 8037 | — |
| Reactant | 1,8-Diazabicyclo(5.4.0)undec-7-ene | HCID 81184 | — |
| Reactant | HCID 86704325 | HCID 86704325 | — |
| Catalyst | Cuprous chloride | HCID 62652 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | HCID 86704324 | HCID 86704324 | 90% |
Reaction Steps
Glacer coupling reaction was carried out using 5-ethynyl-5′-hexyl-2,2′-bithiophene (0.23 g, 0.83 mmol), DBU (0.12 ml, 0.83 mmol), TMEDA (1.87 μl, 1.24 μmol), CuCl (1.60 mg, 1.66 μmol) and acetonitrile (20 ml), and the reaction product was treated in accordance with a conventional method thereby producing an intended product (yield: 90%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09139774B2 |
| Source dataset | uspto-grants-2015_09 |
| ORD ID | ord-3b977faf2f534c8aaca32ca544b98651 |
| Source note | uspto-grants-2015_09 |