4-(Dimethylamino)Benzaldehyde → HCID 178482660, compound

HRID 2284112Notes

Reaction equation

HRID 2284112 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH:20]=[CH:21][C:22]=1[N+:23]([O-])=O)[NH:7][C:8]([C:10]1[CH:11]=[CH:12][C:13]2[N:17]=[N:16][N:15]([CH3:18])[C:14]=2[CH:19]=1)=[O:9])([O-])=O.[CH3:26][N:27]([CH3:36])[C:28]1[CH:35]=[CH:34][C:31]([CH:32]=O)=[CH:30][CH:29]=1>>[CH3:26][N:27]([CH3:36])[C:28]1[CH:35]=[CH:34][C:31]([C:32]2[NH:23][C:22]3[CH:21]=[CH:20][C:6]([NH:7][C:8]([C:10]4[CH:11]=[CH:12][C:13]5[N:17]=[N:16][N:15]([CH3:18])[C:14]=5[CH:19]=4)=[O:9])=[CH:5][C:4]=3[N:1]=2)=[CH:30][CH:29]=1

Participants

3

Reactant 2

HCID 74794-(Dimethylamino)BenzaldehydeHCID 86673953HCID 86673953, compound

Product 1

HCID 178482660HCID 178482660, compound

Procedure

Compound 190 was prepared according to the procedure similar to that described in Scheme III from 3,4-dinitro-N-(1-methyl-6-benzotriazolylcarbonyl)aniline and 4-dimethylaminobenzaldehyde. 1H NMR (500 MHz, DMSO-d6) δ 10.74 (s, 1H), 8.78 (s, 1H), 8.43 (d, J=1.5 Hz, 1H), 8.16 (dd, J=1, 8.5 Hz, 1H), 8.10 (d, J=9 Hz, 2H), 8.01 (d, J=8.5 Hz, 2H), 7.84 (dd, J=2, 9 Hz, 1H), 7.72 (d, J=9 Hz, 1H), 6.96 (d, J=9 Hz, 2H), 4.39 (s, 3H), 3.10 (s, 6H).

Sources & evidence

ORD record
ord-679677d8085f4d3fa3691b41c2a4786f
Source dataset
uspto-grants-2015_09
Patent number
US09144557B2

Reaction notes

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