4-(Dimethylamino)Benzaldehyde → HCID 178491583, compound

HRID 2284123Notes

Reaction equation

HRID 2284123 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH:18]=[CH:19][C:20]=1[N+:21]([O-])=O)[NH:7][C:8](=[O:17])[C:9]1[CH:14]=[CH:13][C:12]([O:15][CH3:16])=[CH:11][CH:10]=1)([O-])=O.[CH3:24][N:25]([CH3:34])[C:26]1[CH:33]=[CH:32][C:29]([CH:30]=O)=[CH:28][CH:27]=1>>[CH3:24][N:25]([CH3:34])[C:26]1[CH:33]=[CH:32][C:29]([C:30]2[NH:21][C:20]3[CH:19]=[CH:18][C:6]([NH:7][C:8](=[O:17])[C:9]4[CH:14]=[CH:13][C:12]([O:15][CH3:16])=[CH:11][CH:10]=4)=[CH:5][C:4]=3[N:1]=2)=[CH:28][CH:27]=1

Participants

3

Reactant 2

HCID 74794-(Dimethylamino)BenzaldehydeHCID 86673963HCID 86673963, compound

Product 1

HCID 178491583HCID 178491583, compound

Procedure

Compound 208 was prepared according to the procedure similar to that described in Scheme III from 3,4-dinitro-N-(4-methoxybenzoyl)aniline and 4-dimethylaminobenzaldehyde. 1H NMR (500 MHz, DMSO-d6) δ 10.41 (s, 1H), 8.39 (d, J=1.5 Hz, 1H), 8.08 (d, J=9.5 Hz, 2H), 8.01 (d, J=7 Hz, 2H), 7.79 (dd, J=2, 9 Hz, 1H), 7.67 (d, J=9 Hz, 1H), 7.09 (d, J=9 Hz, 2H), 6.96 (d, J=9 Hz, 2H), 3.82 (s, 3H), 3.08 (s, 6H).

Sources & evidence

ORD record
ord-46234c5a668b403d8a5af00e9eb3f43a
Source dataset
uspto-grants-2015_09
Patent number
US09144557B2

Reaction notes

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