HRID2285449

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID962

Water

H2O

HCID24290

未命名化合物

结构：C1=Cc2nc1c(-c1ccccc1)c1nc(c(-c3ccccc3)c3ccc([nH]3)c(-c3ccccc3)c3ccc([nH]3)c2-c2ccccc2)C=C1

HCID70186

未命名化合物

HCID517045

Sodium Acetate

C2H3NaO2

2 次

PRODUCTS

生成物

结构：C1=Cc2nc1c(-c1ccccc1)c1ccc([nH]1)c(-c1ccccc1)c1nc(c(-c3ccccc3)c3ccc([nH]3)c2-c2ccccc2)C=C1.[Pd]

HCID136447763

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID176

Acetic Acid

C2H4O2

PROCEDURE

实验过程

Palladium tetraphenylporphyrin is prepared according to the method of operation described by D. W. Thomas and A. E. Martell, J. Amer. Chem. Soc., Vol. 81, p. 5111 (1959). 10 grams of purified tetraphenylporphyrin and 7.7 grams of palladium chloride are placed in 385 ml of acetic acid. The mixture is refluxed for 10 minutes, then 23 grams of sodium acetate are added and the mixture is refluxed for an hour and then a further 23 grams of sodium acetate are added. After 2 additional hours under reflux, the mixture is allowed to cool and poured into 800 ml of water. The precipitate is obtained by filtration, washed with water and, after drying, 12.3 grams of the Pd complex is obtained.

WORKUP

后处理

temperatureThe mixture is refluxed for 10 minutes
temperaturethe mixture is refluxed for an hour
temperatureAfter 2 additional hours under reflux
temperatureto cool
customThe precipitate is obtained by filtration
washwashed with water
customafter drying
custom12.3 grams of the Pd complex is obtained

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e6cd7f3dc9c74a42b4ee6cad4cd79d11
来源数据集: uspto-grants-1982_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04323515
来源说明: uspto-grants-1982_04

反应 SMILES

[CH:1]1[CH:2]=[CH:3][C:4]([C:7]2[C:8]3[NH:12][C:11]([C:13]([C:43]4[CH:44]=[CH:45][CH:46]=[CH:47][CH:48]=4)=[C:14]4[CH:42]=[CH:41][C:16](=[C:17]([C:35]5[CH:36]=[CH:37][CH:38]=[CH:39][CH:40]=5)[C:18]5[CH:34]=[CH:33][C:20](=[C:21]([C:27]6[CH:28]=[CH:29][CH:30]=[CH:31][CH:32]=6)[C:22]6[CH:23]=[CH:24][C:25]=2[N:26]=6)[N:19]=5)[NH:15]4)=[CH:10][CH:9]=3)=[CH:5][CH:6]=1.[Pd:49](Cl)Cl.C([O-])(=O)C.[Na+].O>C(O)(=O)C>[C:43]1([C:13]2[C:11]3[NH:12][C:8](=[CH:9][CH:10]=3)[C:7]([C:4]3[CH:5]=[CH:6][CH:1]=[CH:2][CH:3]=3)=[C:25]3[N:26]=[C:22]([CH:23]=[CH:24]3)[C:21]([C:27]3[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=3)=[C:20]3[NH:19][C:18]([CH:34]=[CH:33]3)=[C:17]([C:35]3[CH:36]=[CH:37][CH:38]=[CH:39][CH:40]=3)[C:16]3=[N:15][C:14]=2[CH:42]=[CH:41]3)[CH:48]=[CH:47][CH:46]=[CH:45][CH:44]=1.[Pd:49]