Chlorotrimethylsilane → [(But-3-yn-2-yl)oxy](trimethyl)silane

HRID 2285668Notes

Reaction equation

[CH3:1][CH:2]([OH:5])[C:3]#[CH:4].[CH3:6][Si:7](Cl)([CH3:9])[CH3:8]>>[CH3:6][Si:7]([CH3:9])([CH3:8])[O:5][CH:2]([C:3]#[CH:4])[CH3:1]

Participants

Reactant 2

HCID 6397Chlorotrimethylsilane

HCID 162393-Butyn-2-ol

Product 1

HCID 28817[(But-3-yn-2-yl)oxy](trimethyl)silaneYield 60%

Procedure

The above compound was prepared in a 60% yield from 35 g of but-3-yn-2-ol and 50.4 g of trimethylsilyl chloride according to the method given in Can. J. Chem. 43, 2004 (1965); b.p. 117°/760 Torr.

Sources & evidence

ORD record: ord-61ee3ab69d70428899b032088e9e87d0
Source dataset: uspto-grants-1982_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04324729

Reaction notes

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