2-[(2-methyl-2-propenyl)oxy]phenol → HCID 22151906, compound

HRID 2285670Notes

Reaction equation

HRID 2285670 reaction equation
C([O:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][C:7]=1[OH:12])C(=C)C.[Al].[CH2:14](C1(O)C=CC=CC1O)[C:15](=[CH2:17])[CH3:16]>>[CH2:16]([C:10]1[CH:11]=[C:6]([OH:5])[C:7](=[CH:8][CH:9]=1)[OH:12])[C:15](=[CH2:14])[CH3:17]

Participants

4

Reactant 3

HCID 785142-[(2-methyl-2-propenyl)oxy]phenol2×HCID 5359268AluminumHCID 70393809HCID 70393809, compound

Product 1

HCID 22151906HCID 22151906, compoundYield 36.6%

Procedure

By carrying out the reaction under the temperature and treatment conditions described in Example 1, starting from ortho-methallyloxyphenol (1.043 g), without using an aluminium derivative, a mixture containing unconverted ortho-methallyloxyphenol (0.189 g), DDHB (0.0126 g), ortho-methallylpyrocatechol (0.520 g) and para-methallylpyrocatechol (0.188 g) is obtained, i.e.:

Workup

  1. customthe reaction under the temperature and treatment conditions

Sources & evidence

ORD record
ord-046763a338894aa1b54bf0ad5a37900a
Source dataset
uspto-grants-1982_04
Patent number
US04324731

Reaction notes

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