Methanethiol → HCID 20544194, compound

HRID 2285719Notes

Reaction equation

HRID 2285719 reaction equation
[CH3:1][SH:2].[N+:3]([C:6]1[CH:11]=[CH:10][C:9]([S:12]Cl)=[C:8]([C:14]([Cl:17])([Cl:16])[Cl:15])[CH:7]=1)([O-:5])=[O:4]>C(OCC)C>[CH3:1][S:2][S:12][C:9]1[CH:10]=[CH:11][C:6]([N+:3]([O-:5])=[O:4])=[CH:7][C:8]=1[C:14]([Cl:17])([Cl:16])[Cl:15]

Participants

4

Reactant 2

HCID 878MethanethiolHCID 127635554-Nitro-2-trichloromethylbenzenesulfenyl chloride

Product 1

HCID 20544194HCID 20544194, compoundYield 88.1%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

At 5° C., 7.2 g of methyl mercaptan is passed over a period of 20 minutes into a solution of 46 g of 4-nitro-2-trichloromethylbenzenesulfenyl chloride in 750 ml of diethyl ether. The reaction mixture is kept at 5° to 10° C. for 2 hours. After the solvent has been distilled off, the residue is recrystallized from ligroin. There is obtained 42 g (88% of theory) of methyldithio-4-nitro-2-trichloromethylbenzene; m.p.: 76° C.

Workup

  1. distillationAfter the solvent has been distilled off
  2. customthe residue is recrystallized from ligroin

Sources & evidence

ORD record
ord-9806cfb64bf34a23a2cee4530c847e80
Source dataset
uspto-grants-1982_04
Patent number
US04324793

Reaction notes

Loading…