HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Cyano-2-mercaptonaphthalene → 2-(4-Nitro-2-trichloromethylphenyldithio)-1-cyanonaphthalene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Cyano-2-mercaptonaphthalene | HCID 12614659 | — |
| Reactant | 4-Nitro-2-trichloromethylbenzenesulfenyl chloride | HCID 12763555 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | 2-(4-Nitro-2-trichloromethylphenyldithio)-1-cyanonaphthalene | HCID 20544190 | 81.3% |
Reaction Steps
30.7 g of 4-nitro-2-trichloromethylbenzenesulfenyl chloride in 500 ml of dioxane is reacted with 18.5 g of 1-cyano-2-mercaptonaphthalene. There is obtained 37 g (81% of theory) of 2-(4-nitro-2-trichloromethylphenyldithio)-1-cyanonaphthalene; m.p.: 170° C. (recrystallized from toluene).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04324793 |
| Source dataset | uspto-grants-1982_04 |
| ORD ID | ord-c97b1efba270490580fe19d408b10c14 |
| Source note | uspto-grants-1982_04 |