Hexamethylenetetramine → Molybdenum hexamethylenetetramine

HRID 2286433Notes

Reaction equation

HRID 2286433 reaction equation
[CH2:1]1[N:6]2[CH2:7][N:8]3[CH2:10][N:4]([CH2:5]2)[CH2:3][N:2]1[CH2:9]3.O[Mo:12](O)(=O)=O.[NH4+].[NH4+].[O-][Mo]([O-])(=O)=O>O>[Mo:12].[CH2:1]1[N:6]2[CH2:7][N:8]3[CH2:10][N:4]([CH2:5]2)[CH2:3][N:2]1[CH2:9]3

Participants

5

Reactant 3

HCID 4101HexamethylenetetramineHCID 61578Diammonium molybdateHCID 82208Molybdic acid

Product 1

HCID 131710930Molybdenum hexamethylenetetramine

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

Hexamethylenetetramine molybdate having a 2/1 molybdenum/hexamethylenetetramine molar ratio was prepared as follows. 10 grams of hexamethylenetetramine was dissolved in 100 ml water heated near reflux temperature. 24.01 grams of commercial, so-called "molybdic acid" (actually at least one ammonium molybdate) was dissolved in 169 ml water heated to reflux temperature. The first solution was added to the second solution.

Workup

  1. temperatureheated
  2. temperaturenear reflux temperature
  3. temperatureheated
  4. temperatureto reflux temperature
  5. additionThe first solution was added to the second solution

Sources & evidence

ORD record
ord-db77f7538ae84c139a8a98c5430575fc
Source dataset
uspto-grants-1981_05
Patent number
US04266051

Reaction notes

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