Methanesulfenyl chloride, trifluoro- → HCID 15572245, compound

HRID 2286586Notes

Reaction equation

HRID 2286586 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([C:9]2[NH:10][CH:11]=[CH:12][C:13]=2[C:14]2[CH:19]=[CH:18][C:17]([O:20][CH3:21])=[CH:16][CH:15]=2)=[CH:5][CH:4]=1.[F:22][C:23]([F:27])([F:26])[S:24]Cl>>[CH3:21][O:20][C:17]1[CH:18]=[CH:19][C:14]([C:13]2[CH:12]=[C:11]([S:24][C:23]([F:27])([F:26])[F:22])[NH:10][C:9]=2[C:6]2[CH:5]=[CH:4][C:3]([O:2][CH3:1])=[CH:8][CH:7]=2)=[CH:15][CH:16]=1

Participants

3

Reactant 2

HCID 67900Methanesulfenyl chloride, trifluoro-HCID 13340632HCID 13340632, compound

Product 1

HCID 15572245HCID 15572245, compound

Procedure

Following the procedure of Example 1, reaction of 2,3-bis(4-methoxyphenyl)pyrrole with trifluoromethanesulfenyl chloride gave 4,5-bis(4-methoxyphenyl)-2-(trifluoromethylthio)pyrrole as a white solid, m.p. 114°-115°.

Sources & evidence

ORD record
ord-1e0702fe7a2949dd83a454b31b844619
Source dataset
uspto-grants-1981_05
Patent number
US04267184

Reaction notes

Loading…