Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Styrene | HCID 7501 | — |
| Reactant | Dichlorosilane | HCID 61330 | — |
| Catalyst | Chlorotris(triphenylphosphine)rhodium(I) | HCID 84599 | — |
| Product | Monophenethyldichlorosilane | HCID 123907249 | 70.9% |
Reaction Steps
Dichlorosilane (31.7 g) (314 millimols), styrene (56.3 g) (541 millimols) and chlorotris(triphenylphosphine)rhodium (0.2182 g) (2.36×10-4 mol) were nitroduced into a 200 ml stainless steel reactor, which was then closed. Reaction was carried out with stirring on heating in an oil bath at 150° C. for 20 hours. The resulting reaction liquid was distilled in vacuo to obtain 45.7 g of mono-β-phenylethyldichlorosilane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04269993 |
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| Source dataset | uspto-grants-1981_05 |
|---|
| ORD ID | ord-a92585f6d84849fc9569a6f8b9a8472e |
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| Source note | uspto-grants-1981_05 |
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