(+-)-alpha-Pinene → L34Amw24TJ

HRID 2287776Notes

Reaction equation

HRID 2287776 reaction equation
[CH2:1](/[C:3](=[CH:6]\[CH2:7][C@@H:8]1[CH2:12][CH:11]=[C:10]([CH3:13])[C:9]1([CH3:15])[CH3:14])/[CH:4]=[O:5])[CH3:2].CC1C2C(C)(C)C(C2)CC=1>>[CH2:1](/[C:3](=[CH:6]\[CH2:7][C@@H:8]1[CH2:12][CH:11]=[C:10]([CH3:13])[C:9]1([CH3:14])[CH3:15])/[CH2:4][OH:5])[CH3:2]

Participants

3

Reactant 2

HCID 6654(+-)-alpha-PineneHCID 86755498(E)-(S)-2-Ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)-2-buten-1-al

Product 1

HCID 8030023L34Amw24TJ

Procedure

(E)-(S)-2-Ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)-2-buten-1-al synthesized from 1R,5R)-α-pinene having an optical purity of 97% e.e. (available from Aldrich) was hydrogenated in the same manner as in Example 2 to obtain the title compound.

Sources & evidence

ORD record
ord-80349c83c84043ee900e445cefced760
Source dataset
uspto-grants-2000_07
Patent number
US06084138

Reaction notes

Loading…