Methanesulfenyl chloride, trifluoro- → 3-Acetyl-1-(2,6-dichloro-4-trifluoromethylphenyl)-4-methylsulfinyl-5-trifluoromethylsulfenylaminopyrazole

HRID 2288041Notes

Reaction equation

[C:1]([C:4]1[C:8]([S:9]([CH3:11])=[O:10])=[C:7]([NH2:12])[N:6]([C:13]2[C:18]([Cl:19])=[CH:17][C:16]([C:20]([F:23])([F:22])[F:21])=[CH:15][C:14]=2[Cl:24])[N:5]=1)(=[O:3])[CH3:2].[F:25][C:26]([F:30])([F:29])[S:27]Cl>>[C:1]([C:4]1[C:8]([S:9]([CH3:11])=[O:10])=[C:7]([NH:12][S:27][C:26]([F:30])([F:29])[F:25])[N:6]([C:13]2[C:14]([Cl:24])=[CH:15][C:16]([C:20]([F:22])([F:21])[F:23])=[CH:17][C:18]=2[Cl:19])[N:5]=1)(=[O:3])[CH3:2]

Participants

Reactant 2

HCID 67900Methanesulfenyl chloride, trifluoro-

HCID 11069398Acetoprole

Product 1

HCID 224560043-Acetyl-1-(2,6-dichloro-4-trifluoromethylphenyl)-4-methylsulfinyl-5-trifluoromethylsulfenylaminopyrazole

Procedure

thiolating 3-acetyl-5-amino-1-(2,6-dichloro-4-trifluoromethylphenyl)-4-methylsulfinylpyrazole with trifluoromethylthio chloride to afford 3-acetyl-1-(2,6dichloro-4-trifluoromethylphenyl)-4-methylsulfinyl-5-trifluoromethylthioaminopyrazole;

Sources & evidence

ORD record: ord-8ceed8089f584bd2bdf5b9c856ecd994
Source dataset: uspto-grants-2000_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06087387

Reaction notes

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