Dimethyl N-cyanodithioiminocarbonate → HCID 20232091, compound

HRID 2290379Notes

Reaction equation

HRID 2290379 reaction equation
[C:1]([N:3]=[C:4](SC)[S:5][CH3:6])#[N:2].[NH:9]([C:11]1[N:12]=[N:13][C:14]([C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[C:15]([CH3:17])[N:16]=1)[NH2:10]>C(Cl)Cl.CO>[NH2:2][C:1]1[N:9]([C:11]2[N:12]=[N:13][C:14]([C:18]3[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=3)=[C:15]([CH3:17])[N:16]=2)[N:10]=[C:4]([S:5][CH3:6])[N:3]=1

Participants

5

Reactant 2

HCID 66289Dimethyl N-cyanodithioiminocarbonateHCID 15586409HCID 15586409, compound

Product 1

HCID 20232091HCID 20232091, compoundYield 89.2%

Reagents, catalysts & solvents 2

HCID 887MethanolSolventHCID 6344DichloromethaneSolvent

Procedure

A solution of dimethyl N-cyanodithioimidocarbonate (2.65 g) in methylene chloride (15 ml) was added to a solution of 3-hydrazino-5-methyl-6-phenyl-1,2,4-triazine (3.52 g) in methanol (20 ml) and stirring was continued for 40 hours at room temperature. The resultant precipitates were collected by filtration, washed with methanol, and dried to give 3-(5-amino-3-methylthio-1,2,4-triazol-1-yl)-5-methyl-6-phenyl-1,2,4-triazine (4.67 g).

Workup

  1. customThe resultant precipitates
  2. filtrationwere collected by filtration
  3. washwashed with methanol
  4. customdried

Sources & evidence

ORD record
ord-17086b48710c4e7fb71da8d7cfc4721d
Source dataset
uspto-grants-1986_10
Patent number
US04616014

Reaction notes

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