HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2290485Generated: October 30, 2026
1,10-Undecanediol → 4-(Hydroxymethyl)cyclohexan-1-one
https://huagongshe.com/reaction/2290485
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 1,10-Undecanediol | HCID 10976255 | — |
| Reactant | Rac-(1s,4s)-4-(hydroxymethyl)cyclohexanol | HCID 12892866 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 4-(Hydroxymethyl)cyclohexan-1-one | HCID 12892867 | 73% |
Reaction Steps
To acetic acid in which Ce (IV)/PFCP (50 mg, 0.027 mmole) and 200 mg of NaBrO3 were dispersed and dissolved, 1.0 mmole of 1,10-undecane diol and 1.0 mmole of 4-hydroxymethyl cyclohexanol were added, respectively. The reaction mixture was heated for three hours at 55° C. and the product was purified with a column chromatography to yield 154 mg (82% yield) of 10-undecane-1-ol and 93 mg (73% yield) of 4-hydroxymethyl cyclohexanone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04617153 |
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| Source dataset | uspto-grants-1986_10 |
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| ORD ID | ord-7d721036405245f7809770c85d0991bd |
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| Source note | uspto-grants-1986_10 |
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