Caprolactam → HCID 178516026, compound

HRID 2290593Notes

Reaction equation

HRID 2290593 reaction equation
C([Mg:3][Br:4])C.[C:5]1(=[O:12])[NH:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6]1>C(OCC)C>[C:5]1(=[O:12])[NH:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6]1.[Br:4][Mg:3]

Participants

4

Reactant 2

HCID 7768CaprolactamHCID 178418443HCID 178418443, compound

Product 1

HCID 178516026HCID 178516026, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

In a second flask a 0.23 molar bromomagnesium caprolactam solution was prepared by adding 15 ml of a 3 molar ethyl magnesium bromide in diethyl ether solution to 200 gms dry caprolactam. Then 2.12 ml (2.0 gm) of a polyoxypropylene diamine (approximate m.w. 230) was added. The equivalents of primary and secondary amines of the polyfunctional amine were 30 percent of the acyl lactam group equivalent of the acyl lactam functionalized material. The material of the two flasks were injected into a mold as described above for Example 1. After 5 minutes, the casting was removed from the mold to give a nylon block copolymer containing 40% polyether.

Workup

  1. customthe casting was removed from the mold

Sources & evidence

ORD record
ord-9d60e19db8114a28ae453bfcb83cf5d3
Source dataset
uspto-grants-1986_10
Patent number
US04617355

Reaction notes

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