HuagongsheHuagongshe Chemistry Print Report · For research reference only
4,4'-Dibromobiphenyl → Biphenyl
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4,4'-Dibromobiphenyl | HCID 7110 | — |
| Reactant | Sodium Carbonate | HCID 10340 | — |
| Reactant | HCID 178418950 | HCID 178418950 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | Biphenyl | HCID 7095 | — |
| Product | 4-Bromobiphenyl | HCID 7101 | — |
Reaction Steps
To a solution of 3.1 g of 4,4'-dibromo biphenyl in 30 ml tetrahydrofuran was added 3.5 g sodium carbonate and 400 mg of 5% palladium on carbon. To this reaction mixture there was added 2.5 g sodium hypophosphite monohydrate in about 20 ml water. After about one hour, a GC analysis established that all of the starting material had reacted to yield primarily biphenyl with a trace amount of p-mono-bromobiphenyl.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04618686 |
| Source dataset | uspto-grants-1986_10 |
| ORD ID | ord-bdbb6731b94b412e8ae36996f9466339 |
| Source note | uspto-grants-1986_10 |