4-(Benzyloxy)-3-methoxybenzaldehyde → HCID 54185292, compound

HRID 2290817Notes

Reaction equation

HRID 2290817 reaction equation
[CH2:1]([O:8][C:9]1[CH:16]=[CH:15][C:12]([CH:13]=O)=[CH:11][C:10]=1[O:17][CH3:18])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[O:19]=[C:20]([CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH3:33])[CH2:21]P(=O)(OC)OC>>[CH2:1]([O:8][C:9]1[CH:16]=[CH:15][C:12]([CH:13]=[CH:21][C:20](=[O:19])[CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH3:33])=[CH:11][C:10]=1[O:17][CH3:18])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 755064-(Benzyloxy)-3-methoxybenzaldehydeHCID 13390134Dimethyl (2-oxooctyl)phosphonate

Product 1

HCID 54185292HCID 54185292, compoundYield 72.7%

Procedure

By following the procedure as in Reference Example 1(a) using 1.2 g of 4-benzyloxy-3-methoxybenzaldehyde and 1.53 g of dimethyl 2-oxooctylphosphonate, 1.27 g of 1-(4-benzyloxy-3-methoxyphenyl)-1-nonen-3-one was obtained. Melting point 78°-81° C.

Sources & evidence

ORD record
ord-812955293b4a47bd808c011aa78f6e59
Source dataset
uspto-grants-1986_10
Patent number
US04618627

Reaction notes

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