Diketene → HCID 13669722, compound

HRID 2290831Notes

Reaction equation

[CH2:1]=[C:2]1[O:6][C:4](=[O:5])[CH2:3]1.[O:7]([CH2:14][CH:15]([OH:17])[CH3:16])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1>>[C:4]([O:17][CH:15]([CH3:16])[CH2:14][O:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)(=[O:5])[CH2:3][C:2]([CH3:1])=[O:6]

Participants

Reactant 2

HCID 12661Diketene

HCID 928391-Phenoxy-2-propanol

Product 1

HCID 13669722HCID 13669722, compound

Procedure

In a similar manner, diketene was reacted with 1-phenoxy-2-propanol to obtain 1-methyl-2-(phenoxy)ethyl acetoacetate, BP 115°-122° C./0.05-0.1 mm.

Sources & evidence

ORD record: ord-1070f2cd3eb647a0ac7c1db7e05beaf6
Source dataset: uspto-grants-1986_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04618678

Reaction notes

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