Sulfuric Acid → HCID 54185359, compound

HRID 2290974Notes

Reaction equation

HRID 2290974 reaction equation
Cl[C:2]1[C:3]([N+:16]([O-:18])=[O:17])=[C:4]([CH:13]=[CH:14][CH:15]=1)[C:5]([C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)=[O:6].S(=O)(=O)(O)O.[N+:24]([O-:27])([O-])=[O:25].[Na+].C(Cl)[Cl:30]>>[Cl:30][C:15]1[CH:14]=[CH:13][C:4]([C:5]([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=2)=[O:6])=[C:3]([N+:16]([O-:18])=[O:17])[C:2]=1[N+:24]([O-:27])=[O:25]

Participants

5

Reactant 4

HCID 1118Sulfuric AcidHCID 6344DichloromethaneHCID 24268Sodium NitrateHCID 15634746HCID 15634746, compound

Product 1

HCID 54185359HCID 54185359, compoundYield 95.5%

Procedure

This crude chloronitrobenzophenone was dissolved in 500 ml of methylene chloride and 250 g (2.5 mol) of concentrated sulfuric acid and 93.5 g (1.1 mol) of sodium nitrate were added thereto. The mixture was reacted at a temperature of 35° to 40° C. for 7 hours. After the completion of the reaction, 500 ml of ice water was carefully added thereto. Methylene chloride was removed by heating. The precipitated light brown particulate material was recovered by filtration, washed with water, and dried to give 293 g (over-all yield 95.5%) of crude chlorodinitrobenzophenone.

Workup

  1. customThe mixture was reacted at a temperature of 35° to 40° C. for 7 hours
  2. additionwas carefully added
  3. customMethylene chloride was removed
  4. temperatureby heating
  5. filtrationThe precipitated light brown particulate material was recovered by filtration
  6. washwashed with water
  7. customdried

Sources & evidence

ORD record
ord-15d2e7f9477d4e478166a4c3956a2a41
Source dataset
uspto-grants-1986_10
Patent number
US04618714

Reaction notes

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