HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosphorus oxychloride → 4-Chloro-3,5-dinitrobenzene-1-sulfonyl chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosphorus oxychloride | HCID 24813 | — |
| Reactant | Benzenesulfonic acid, 4-chloro-3,5-dinitro-, potassium salt | HCID 3036952 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Solvent | Sulfolane | HCID 31347 | — |
| Product | 4-Chloro-3,5-dinitrobenzene-1-sulfonyl chloride | HCID 14323986 | — |
Reaction Steps
760 g (2 moles) 3,5-dinitro-4-chlorobenzenesulfonic acid potassium salt (approx. 85%) and 614 g (4 moles) phosphorus oxychloride were reacted as in Example 1(a) in 800 ml acetonitrile and 800 ml tetramethylenesulfone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04797427 |
| Source dataset | uspto-grants-1989_01 |
| ORD ID | ord-886594b4c60146f0b53deefa13b970a5 |
| Source note | uspto-grants-1989_01 |