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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2291810Generated: November 1, 2026

Trimethylolpropane → Toluene 2,4-Diisocyanate

https://huagongshe.com/reaction/2291810

Reaction equation

Participants

RoleNameHCIDCharge
ReactantTrimethylolpropaneHCID 6510—
ReactantDiphenylmethane diisocyanateHCID 7570—
ReactantToluene 2,4-DiisocyanateHCID 11443—
Reactant1,5-Naphthalene diisocyanateHCID 18503—
Reactant1,3-DiisocyanatobenzeneHCID 31262—
ReactantHCID 21863440HCID 21863440—
ReactantHCID 21885215HCID 21885215—
ReactantHCID 21900977HCID 21900977—
ReactantHCID 21908553HCID 21908553—
ReactantHCID 21954401HCID 21954401—
ReactantHCID 21954416HCID 21954416—
ProductToluene 2,4-DiisocyanateHCID 11443—
ProductHexamethylene diisocyanateHCID 13192—

Reaction Steps

Specific examples of the polyisocyanates include isocyanates, such as ethane diisocyanate, butane diisocyanate, hexane diisocyanate, 2,2-dimethylpentane diisocyanate, 2,2,4-trimethylpentane diisocyanate, decane diisocyanate, ω,ω'-diisocyanate-1,3-dimethylbenzoyl, ω,ω'-diisocyanate-1,2-dimethylcyclohexane diisocyanate, ω,ω'-diisocyanate-1,4-diethylbenzoyl, ω,ω'-diisocyanate-1,5-dimethylnaphthalene, ω,ω'-diisocyanate-n-propylbiphenyl, 1,3-phenylene diisocyanate, 1-methylbenzoyl-2,4-diisocyanate, 1,3-dimethylbenzol-2,6-diisocyanate, naphthalene-1,4-diisocyanate, 1,1'-dinaphthyl-2,2'-diisocyanate, biphenyl-2,4'-diisocyanate, 3,3'-dimethylbiphenyl-4,4'-diisocyanate, diphenylmethane-4,4'-diisocyanate, 2,2'-dimethyldiphenylmethane-4,4'-diisocyanate, 3,3'-dimethoxydiphenylmethane-4,4'-diisocyanate, 4,4'-diethoxydiphenylmethane-4,4'-diisocyanate, 1-methylbenzol-2,4,6-triisocyanate, 1,3,5-trimethylbenzol-2,4,6-triisocyanate, diphenylmethane-2,4,4'-triisocyanate, triphenylmethane-4,4',4"-triisocyanate, tolylene diisocyanate, 1,5-naphthylene diisocyanate, etc.; dimers or trimers (adducts) of these isocyanates; and adducts of these isocyanates with di- or trihydric alcohols. The adducts of the isocyanates include an adduct of tolylene diisocyanate with trimethylolpropane, an adduct of 3 mols of tolylene diisocyanate, an adduct of 3 mols of hexamethylene diisocyanate, an adduct of 2 mols of hexamethylene diisocyanate, and adducts formed among the above-recited isocyanates.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04798755
Source datasetuspto-grants-1989_01
ORD IDord-aa95d7e562ad4427b0cdedd3d024cfa0
Source noteuspto-grants-1989_01