HRID2292284

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：[Cu].c1ccc2c(c1)-c1nc-2nc2[n-]c(nc3nc(nc4[n-]c(n1)c1ccccc41)-c1ccccc1-3)c1ccccc21

HCID499989

[29H,31H-Phthalocyaninato(2-)-kappaN29,kappaN31]cuprate(2-)

C32H16CuN8-2

PRODUCTS

生成物

结构：[Cu].c1ccc2c(c1)C1=NC2=NC2=NC(=NC3=NC(=NC4=NC(=N1)c1ccccc14)c1ccccc13)c1ccccc12

HCID475701

未命名化合物

收率 91.2%

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID93698

(Octahydro-1H-4,7-methanoinden-5-yl)methanol

C11H18O

溶剂HCID962

Water

H2O

2 次

PROCEDURE

实验过程

14.8 g of crude β-copper phthalocyanine, 0.2 g of 8-hydroxymethyltricyclo[5.2.1.02,6 ]decane [TCD alcohol M®, ex Hoechst], 125 g of water and 400 g of glass beads with a diameter of 3.5-4.0 mm are ground for 15 hours at 320 rpm, with water cooling, in a 500 ml glass bead mill of 8 cm diameter. The pigment suspension is separated from the glass beads, which are washed with water. The suspension is then filtered and the filter cake is dried at 70°-80° C. in a vacuum drying cabinet, affording 13.5 g of blue copper phthalocyanine pigment which, when incorporated in powder form into varnishes, gives strong finishes.

WORKUP

后处理

customfor 15 hours
customThe pigment suspension is separated from the glass beads, which
washare washed with water
filtrationThe suspension is then filtered
customthe filter cake is dried at 70°-80° C. in a vacuum
customdrying cabinet

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-d204d1de433b4ab386ab24a7cd778e46
来源数据集: uspto-grants-1989_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04801702
来源说明: uspto-grants-1989_01

反应 SMILES

[CH:1]1[CH:6]=[C:5]2[C:7]3[N-:34][C:33]([C:4]2=[CH:3][CH:2]=1)=[N:32][C:30]1=[N:31][C:23]([C:24]2[C:29]1=[CH:28][CH:27]=[CH:26][CH:25]=2)=[N:22][C:20]1[N-:21][C:13](=[C:14]2[C:19]=1[CH:18]=[CH:17][CH:16]=[CH:15]2)[N:12]=[C:11]1[C:35]2[C:40]([C:9](=[N:10]1)[N:8]=3)=[CH:39][CH:38]=[CH:37][CH:36]=2.[Cu:41]>OCC1CC2CC1C1C2CCC1.O>[CH:38]1[CH:39]=[C:40]2[C:9]3[N:10]=[C:11]([C:35]2=[CH:36][CH:37]=1)[N:12]=[C:13]1[C:14]2[C:19]([C:20](=[N:21]1)[N:22]=[C:23]1[C:24]4[C:29]([C:30](=[N:31]1)[N:32]=[C:33]1[C:4]5[C:5]([C:7](=[N:34]1)[N:8]=3)=[CH:6][CH:1]=[CH:2][CH:3]=5)=[CH:28][CH:27]=[CH:26][CH:25]=4)=[CH:18][CH:17]=[CH:16][CH:15]=2.[Cu:41]