HCID 178428697, compound → Tricyclodecanemethanol

HRID 2292285Notes

Reaction equation

HRID 2292285 reaction equation
CC1C(Cl)=CC(S([O-])(=O)=O)=C(NN=[C:15]2[C:25]3[C:20](=[CH:21][CH:22]=[CH:23][CH:24]=3)[CH:19]=[CH:18][C:16]2=O)C=1.CC1C(Cl)=CC(S([O-])(=O)=O)=C(NN=C2C3C(=CC=CC=3)C=C[C:41]2=[O:42])C=1.[Ba+2]>C1C=C2C3[N-]C(C2=CC=1)=NC1=NC(C2C1=CC=CC=2)=NC1[N-]C(=C2C=1C=CC=C2)N=C1C2C(C(=N1)N=3)=CC=CC=2.[Cu]>[OH:42][CH2:41][CH:24]1[CH2:23][CH:22]2[CH2:15][CH:25]1[CH:20]1[CH:21]2[CH2:16][CH2:18][CH2:19]1

Participants

3

Reactant 1

HCID 178428697HCID 178428697, compound

Product 1

HCID 93698Tricyclodecanemethanol

Reagents, catalysts & solvents 1

HCID 499989Alpha.-Copper phthalocyanineCatalyst

Procedure

The procedure of Example 6 is repeated, replacing the β-copper phthalocyanine pigment by 14.2 g of the azo pigment, C.I. Pigment Red 166, obtained direct from the synthesis and 0.8 g of 8-hydroxymethyltricyclo[5.2.1.02,6 ]decane [TCD alcohol M®, ex Hoechst] and grinding for 15 instead of 4 hours, to give a high yield azo pigment of the same structure which can be very readily incorporated in plastics and varnishes.

Sources & evidence

ORD record
ord-4cecfaa0b02f4a05977d31a3af3e83e5
Source dataset
uspto-grants-1989_01
Patent number
US04801702

Reaction notes

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