Diethyl (octan-2-yl)propanedioate → 2-Hexylpropane-1,3-diol

HRID 2292398Notes

Reaction equation

HRID 2292398 reaction equation
C([O:3][C:4]([CH:6]([C:15](OCC)=[O:16])[CH:7]([CH2:9][CH2:10][CH2:11][CH2:12][CH2:13]C)C)=O)C.[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH2:7]([CH:6]([CH2:4][OH:3])[CH2:15][OH:16])[CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

Participants

3

Reactant 2

HCID 13463462Diethyl (octan-2-yl)propanedioateHCID 21226445Aluminium lithium hydride

Product 1

HCID 2684842-Hexylpropane-1,3-diol

Procedure

Quantities: compound from Example 2 (72.2 g, 0.3 mol) and lithium aluminum hydride (20 g, 0.53 mol). The experimental procedure was as described in Example 6. The pure product isolated by distillation under reduced pressure.

Workup

  1. customThe pure product isolated by distillation under reduced pressure

Sources & evidence

ORD record
ord-18a50685118d4f61bd81460bda543007
Source dataset
uspto-grants-1997_11
Patent number
US05683623

Reaction notes

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