Diethyl undecan-2-ylpropanedioate → 2-Nonylpropane-1,3-diol

HRID 2292401Notes

Reaction equation

HRID 2292401 reaction equation
C([O:3][C:4]([CH:6]([C:18](OCC)=[O:19])[CH:7]([CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16]C)C)=O)C.[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH2:7]([CH:6]([CH2:4][OH:3])[CH2:18][OH:19])[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

Participants

3

Reactant 2

HCID 239016Diethyl undecan-2-ylpropanedioateHCID 21226445Aluminium lithium hydride

Product 1

HCID 39697442-Nonylpropane-1,3-diol

Procedure

Quantities: compound from Example 5 (76.5 g, 0.28 mol) and lithium aluminum hydride (23 g, 0.6 mol). The experimental procedure was as described in Example 6.

Sources & evidence

ORD record
ord-a11852d560b14718ba3d8a4461093fad
Source dataset
uspto-grants-1997_11
Patent number
US05683623

Reaction notes

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