HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosphorus tribromide → 2,3-Dichloro-5-nitrophenylmethyl bromide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosphorus tribromide | HCID 24614 | — |
| Reactant | 2,3-Dichloro-5-nitrobenzyl alcohol | HCID 21478123 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 2,3-Dichloro-5-nitrophenylmethyl bromide | HCID 21478112 | 230.6% |
Reaction Steps
By the method of Example 1, Step B, 61.90 grams (0.279 mole) of 2,3-dichloro-5-nitrophenylmethanol and 26.41 grams (0.098 mole) of phosphorus tribromide were reacted in 800 mL of toluene, yielding 64.38 grams of 2,3-dichloro-5-nitrophenylmethyl bromide as a golden oil which solidified upon standing. The NMR spectrum was consistent with the proposed structure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05683966 |
| Source dataset | uspto-grants-1997_11 |
| ORD ID | ord-b26b29f63d264e75bdaf06ae5f6edaa4 |
| Source note | uspto-grants-1997_11 |