4-Chloro-3-nitrobenzoic acid → 4-(allylamino)-3-nitrobenzoic acid

HRID 2292992Notes

Reaction equation

HRID 2292992 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6](N)[CH:7]=[CH:8][C:9]=1[NH:10][CH2:11][CH:12]=[CH2:13])([O-:3])=[O:2].ClC1C=CC([C:20]([OH:22])=[O:21])=CC=1[N+]([O-])=O>>[N+:1]([C:4]1[CH:5]=[C:6]([CH:7]=[CH:8][C:9]=1[NH:10][CH2:11][CH:12]=[CH2:13])[C:20]([OH:22])=[O:21])([O-:3])=[O:2]

Participants

3

Reactant 2

HCID 73204-Chloro-3-nitrobenzoic acidHCID 235000362-Nitro-N~1~-(prop-2-en-1-yl)benzene-1,4-diamine

Product 1

HCID 117155314-(allylamino)-3-nitrobenzoic acid

Procedure

Synthesis and working up as for compound 1, but with 4-chloro-3-nitrobenzoic acid instead of 4-fluoro-3-nitroaminobenzene. Yellow crystals, melting point 195°-200° C.

Workup

  1. customSynthesis

Sources & evidence

ORD record
ord-aa1f2bcaee274f7ea292346926f4c329
Source dataset
uspto-grants-1997_11
Patent number
US05685881

Reaction notes

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