2-Ethyl-1,3-Hexanediol → 2-Ethyl-1-triethoxysiloxy-3-hexanol

HRID 2292997Notes

Reaction equation

HRID 2292997 reaction equation
[CH2:1]([CH:3]([CH:6]([OH:10])[CH2:7][CH2:8][CH3:9])[CH2:4][OH:5])[CH3:2].Cl[Si:12]([O:19][CH2:20][CH3:21])([O:16][CH2:17][CH3:18])[O:13][CH2:14][CH3:15].C1(NC2CCCCC2)CCCCC1>C(O)C>[CH2:1]([CH:3]([CH:6]([OH:10])[CH2:7][CH2:8][CH3:9])[CH2:4][O:5][Si:12]([O:19][CH2:20][CH3:21])([O:16][CH2:17][CH3:18])[O:13][CH2:14][CH3:15])[CH3:2]

Participants

5

Reactant 3

HCID 72112-Ethyl-1,3-HexanediolHCID 7582DicyclohexylamineHCID 78398Triethoxychlorosilane

Product 1

HCID 537572682-Ethyl-1-triethoxysiloxy-3-hexanolYield 50%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

2-Ethyl-1,3-hexanediol was mixed with chlorotriethoxysilane and dicyclohexylamine in a 1:1:1 ratio at 0° C. in absolute ethanol. The resulting product, 2-ethyl-1-triethoxysiloxy-3-hexanol, was obtained in 50% yield and was dissolved to a 10% by weight solution in a 50/50 by volume mixture of ethanol/cyclomethicone.

Sources & evidence

ORD record
ord-c97bb95cf8f6437b8dacbf5c66cdf630
Source dataset
uspto-grants-1997_11
Patent number
US05686065

Reaction notes

Loading…