HRID2293061

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O[SiH2]OCCCCCCCCCCCCCCCC(c1ccccc1)c1ccccc1

HCID131718749

未命名化合物

结构：O[Ge]O.c1ccc2c(c1)-c1nc-2nc2[nH]c(nc3nc(nc4[nH]c(n1)c1ccccc41)-c1ccccc1-3)c1ccccc21

HCID178526211

未命名化合物

2 次

PRODUCTS

生成物

结构：c1ccc(C(CCCCCCCCCCCCCCCO[SiH2][O][Ge][O][SiH2]OCCCCCCCCCCCCCCCC(c2ccccc2)c2ccccc2)c2ccccc2)cc1.c1ccc2c(c1)-c1nc-2nc2[nH]c(nc3nc(nc4[nH]c(n1)c1ccccc41)-c1ccccc1-3)c1ccccc21

HCID137331263

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID31275

1,4-Dioxane

C4H8O2

PROCEDURE

实验过程

Variant b: 2 g (3.24 mmol) of dihydroxygermanium-phthalocyanine are boiled at reflux with 2 equivalents of diphenylhexadecyloxysilanol in 210 ml of dioxane for 39 hours. After 24 hours, 500 mg of dihydroxygermanium-phthalocyanine are added. The reaction mixture is allowed to cool and the residue is chromatographed on basic aluminium oxide (Alox B) using pure hexane and hexane/ethyl acetate (4:1) in succession as eluants. The product-containing fractions are combined and concentrated. The residue is recrystallised from pentane at -20° C., yielding blue crystals of bis(diphenylhexadecyloxy-siloxy)-germanium-phthalocyanine.

WORKUP

后处理

temperatureto cool
customthe residue is chromatographed on basic aluminium oxide (Alox B)
concentrationconcentrated
customThe residue is recrystallised from pentane at -20° C.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-3083faddddb64e278589a7989136f615
来源数据集: uspto-grants-1997_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05686439
来源说明: uspto-grants-1997_11

反应 SMILES

[OH:1][Ge:2][OH:3].[CH:4]1[CH:5]=[CH:6][C:7]2[C:8](=[C:10]3[N:42]=[C:41]4[N:43]=[C:34]([C:35]5[CH:36]=[CH:37][CH:38]=[CH:39][C:40]=54)[N:33]=[C:31]4[NH:32][C:24]([C:25]5[CH:26]=[CH:27][CH:28]=[CH:29][C:30]=54)=[N:23][C:21]4=[N:22][C:14]([C:15]5[CH:16]=[CH:17][CH:18]=[CH:19][C:20]=54)=[N:13][C:12]=2[NH:11]3)[CH:9]=1.[C:44]1([CH:50]([C:69]2[CH:74]=[CH:73][CH:72]=[CH:71][CH:70]=2)[CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][CH2:59][CH2:60][CH2:61][CH2:62][CH2:63][CH2:64][CH2:65][O:66][SiH2:67]O)[CH:49]=[CH:48][CH:47]=[CH:46][CH:45]=1>O1CCOCC1>[C:48]1([CH:41]([C:40]2[CH:35]=[CH:36][CH:37]=[CH:38][CH:39]=2)[CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][CH2:59][CH2:60][CH2:61][CH2:62][CH2:63][CH2:64][CH2:65][O:66][SiH2:67][O:1][Ge:2][O:3][SiH2:67][O:66][CH2:65][CH2:64][CH2:63][CH2:62][CH2:61][CH2:60][CH2:59][CH2:58][CH2:57][CH2:56][CH2:55][CH2:54][CH2:53][CH2:52][CH2:51][CH:50]([C:69]2[CH:70]=[CH:71][CH:72]=[CH:73][CH:74]=2)[C:44]2[CH:49]=[CH:48][CH:47]=[CH:46][CH:45]=2)[CH:47]=[CH:46][CH:45]=[CH:44][CH:49]=1.[CH:5]1[CH:4]=[CH:9][C:8]2[C:7](=[C:12]3[N:13]=[C:14]4[N:22]=[C:21]([C:20]5[CH:19]=[CH:18][CH:17]=[CH:16][C:15]=54)[N:23]=[C:24]4[NH:32][C:31]([C:30]5[CH:29]=[CH:28][CH:27]=[CH:26][C:25]=54)=[N:33][C:34]4=[N:43][C:41]([C:40]5[CH:39]=[CH:38][CH:37]=[CH:36][C:35]=54)=[N:42][C:10]=2[NH:11]3)[CH:6]=1