HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chlorine → 9-Chloro-5H-dibenz[b,e]azepin-6,11-dione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chlorine | HCID 24526 | — |
| Reactant | 5H-Dibenz(b,e)azepine-6,11-dione | HCID 70836 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 9-Chloro-5H-dibenz[b,e]azepin-6,11-dione | HCID 54011703 | — |
Reaction Steps
A mixture of 11.15 g of 5H-dibenz[b,e]azepin-6,11-dione and 600 ml of glacial acetic acid is heated on a steam bath until the solid dissolves. To the solution (70° C.) is added chlorine gas chlorine is bubbled through the solution until a precipitate begins to form. The mixture is allowed to cool to room temperature and is filtered to give 7.3 g of product, m.p. 290° C. to 295° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05686445 |
| Source dataset | uspto-grants-1997_11 |
| ORD ID | ord-1346ecad4f564c09abf3c95bf41fe04b |
| Source note | uspto-grants-1997_11 |