HuagongsheHuagongshe Chemistry Print Report · For research reference only
ethyl (RS)-alpha-[(tert-butylsulfonyl)methyl]hydrocinnamate → HCID 67723670, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | ethyl (RS)-alpha-[(tert-butylsulfonyl)methyl]hydrocinnamate | HCID 14158057 | — |
| Reactant | HCID 21475070 | HCID 21475070 | — |
| Reactant | HCID 86751633 | HCID 86751633 | — |
| Product | HCID 67723670 | HCID 67723670 | — |
Reaction Steps
This compound is prepared in a manner analogous to Example 1(d) by the enzymatic hydrolysis of ethyl (S)-α-[(tert-butylsulphonyl)methyl]-2-thiophenepropionate which, in turn, is prepared analogously to the synthesis, described in EPA 0236734, of ethyl (RS)-α-[(tert-butylsulphonyl)methyl]hydrocinnamate from diethyl 2-thionylmethylmalonate (P. Cagniant et al., Bull. Soc. Chim. Fr. 1954, 1349). MS: 318 (M)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05688946 |
| Source dataset | uspto-grants-1997_11 |
| ORD ID | ord-37ea2a94eec6485cb6b5e132fdaa5f55 |
| Source note | uspto-grants-1997_11 |