HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2295399Generated: October 27, 2026
Peracetic Acid → 4,4'-Dimethyl-2,2'-bipyridyl 1-Oxide
https://huagongshe.com/reaction/2295399
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Peracetic Acid | HCID 6585 | — |
| Reactant | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | 4,4'-Dimethyl-2,2'-bipyridyl 1-Oxide | HCID 13586792 | — |
Reaction Steps
27.6 g (0.15 mol) of 4,4'-dimethyl-2,2'-bipyridine are dissolved in 300 ml of dichloromethane. 86 ml of a 1.837-molar solution of peracetic acid in ethyl acetate are added dropwise at 23°-28° C. After stirring for 50 hours at 23° C., the mixture is concentrated in vacuo. 27.2 g (90% of theory) of 4.4'-dimethyl-2,2'-bipyridine 1-oxide crystallise from ethylbenzene/petroleum ether; melting point 80°-130° C. (over a range).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04424359 |
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| Source dataset | uspto-grants-1984_01 |
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| ORD ID | ord-56bc2bd8fefa4cdaa3160f93b0e02475 |
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| Source note | uspto-grants-1984_01 |
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