HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Methylresorcinol → HCID 20282956, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Methylresorcinol | HCID 11843 | — |
| Reactant | HCID 20282950 | HCID 20282950 | — |
| Reactant | HCID 20282951 | HCID 20282951 | — |
| Reactant | HCID 23721279 | HCID 23721279 | — |
| Reactant | HCID 70506655 | HCID 70506655 | — |
| Solvent | Methanol | HCID 887 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | HCID 20282956 | HCID 20282956 | — |
| Product | HCID 20282979 | HCID 20282979 | — |
| Product | HCID 20282993 | HCID 20282993 | — |
Reaction Steps
2,6-Dihydroxytoluene was converted by the methods of Example 2(a), (b) and (c) to methyl 2-[3-benzyloxy-6-formyl-2-methylphenoxy]acetate, mp 64°-66°, which by the methods of Example 2(d) and (e) and Example 5(b) gave successively methyl 6-benzyloxy-7-methylbenzofuran-2-carboxylate, mp 117°-120° (from ethyl acetate), methyl 6-hydroxy-7-methylbenzofuran-2-carboxylate, mp 144°-147° (decomp.) and methyl 6-[3-(4-acetyl-3-hydroxy-2-propylphenoxy)propoxy]-7-methylbenzofuran-2-carboxylate, mp 123°-124° (from methanol).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04424231 |
| Source dataset | uspto-grants-1984_01 |
| ORD ID | ord-5162902f285c49268f84926b3dd3e606 |
| Source note | uspto-grants-1984_01 |