Pinacolone → 2,2-Dimethyl-6,8-decadien-3-one

HRID 2295701Notes

Reaction equation

Cl[CH2:2][CH:3]=[CH:4][CH:5]=[CH:6][CH3:7].[CH3:8][C:9]([CH3:14])([CH3:13])[C:10](=[O:12])[CH3:11]>>[CH3:8][C:9]([CH3:14])([C:10](=[O:12])[CH2:11][CH2:2][CH:3]=[CH:4][CH:5]=[CH:6][CH3:7])[CH3:13]

Participants

Reactant 2

HCID 6416Pinacolone

HCID 5570091-Chlorohexa-2,4-diene

Product 1

HCID 537861612,2-Dimethyl-6,8-decadien-3-oneYield 100%

Procedure

According to the procedure described in Example 2, from 19.4 g of 1-chloro-2,4-hexadiene and 17.4 g of 3,3-dimethyl-butan-2-one there are obtained 30 g of crude 2,2-dimethyl-6,8-decadien-3-one which are subjected to a fractional distillation.

Sources & evidence

ORD record: ord-b13fe8166826485981c98f6da83e7097
Source dataset: uspto-grants-1984_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04426321

Reaction notes

Loading…