HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → Carbonic acid, 1-chloroethyl ethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Pyridine | HCID 1049 | — |
| Reactant | 1-Chloroethyl chloroformate | HCID 521305 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | Carbonic acid, 1-chloroethyl ethyl ester | HCID 162095 | — |
Reaction Steps
Ethanol (2.3 g) was dissolved in dichloromethane (50 ml) and pyridine (4.0 g) was added. It was reacted with 1-chloroethyl chloroformate (7.5 g) as described above. On work up it gave 7.5 g of a pale mobile liquid (desired product). NMR (CDCl3) δ1.36 (3H, t, J=7 Hz, OCH2CH3), 1.88 (3H, d, J=7 Hz, ClCH2CH3), 4.36 (2H, q, J=7 Hz, OCH2CH3) and 6.41 (1H, q, J=7 Hz, CH3CHCl).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04426391 |
| Source dataset | uspto-grants-1984_01 |
| ORD ID | ord-13d46f2e9a934632b745ebfe3271102b |
| Source note | uspto-grants-1984_01 |